CRYSTAL SPECTRA OF HEXAUREA COMPLEXES .2. ABSORPTION AND EMISSION IN CRYSTALS CONTAINING HEXAUREA CHROMIUM (3) ION

被引：29

作者：

DINGLE, R

机构：

[1] Department for Physical Chemistry, H. C. ØRsted Institute, University of Copenhagen, Copenhagen

[2] Bell Telephone Laboratories, Incorporated, Murray Hill, NJ

来源：

JOURNAL OF CHEMICAL PHYSICS | 1969年 / 50卷 / 05期

关键词：

D O I：

10.1063/1.1671313

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Absorption and emission bands have been observed in crystals containing the hezaurea chromium (III) ion. The moderately sharp features in the region 14 160-14 250 cm-1 have been examined in some detail in the temperature range 1.5°-300°K. A broad emission band has been seen at 12 300 cm-1 and is considered to be the 4T2g→4A2g transition. Detailed radiative lifetime and quantum efficiency measurements lead to a proposal that includes the possible identification of the (0, 0) 4T2g(Oh) transition.

引用

页码：1952 / &

共 22 条

[1]

BARBIERI GA, 1913, ATTI ACCAD NAZ LINCE, V22, P867

[2] CRYSTAL SPECTRA OF HEXAUREA COMPLEXES .I. JAHN-TELLER EFFECT IN HEXAUREA TITANIUM (3) TRIODIDE [J].