GROUP ADDITIVITY THERMODYNAMICS FOR DISSOLUTION OF SOLID CYCLIC DIPEPTIDES INTO WATER

被引：92

作者：

MURPHY, KP ^{[1
]}

GILL, SJ ^{[1
]}

机构：

[1] UNIV COLORADO, DEPT CHEM & BIOCHEM, BOULDER, CO 80309 USA

来源：

THERMOCHIMICA ACTA | 1990年 / 172卷

基金：

美国国家卫生研究院;

关键词：

D O I：

10.1016/0040-6031(90)80555-D

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The thermodynamics of dissolution of a set of cyclic dipeptide solids into water has been studied in order to establish the energetic contributions of various groups which determine protein folding. The techniques are described and the results are interpreted in terms of a group additivity scheme. It is shown that this kind of group additivity leads to linear correlations (either entropy change or enthalpy change with heat capacity change) which have been observed for protein denaturation and the dissolution of apolar compounds [1]. © 1990.

引用

页码：11 / 20

页数：10

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