AN UNEXPECTED STEREOCHEMICAL CONTROL OF ALKENE FORMATION BY THE CHOICE OF RADICAL INITIATOR - THE REVERSIBLE ADDITION OF (ME3SI)3SI. RADICALS TO ALKENES

被引：13

作者：

FERRERI, C

BALLESTRI, M

CHATGILIALOGLU, C

机构：

[1] CNR, CEA, I CO, I-40064 OZZANO DELL EMILIA, ITALY

[2] UNIV NAPLES, DIPARTIMENTO CHIM ORGAN & BIOL, I-80134 NAPLES, ITALY

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 32期

关键词：

D O I：

10.1016/S0040-4039(00)60699-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Tris(trimethylsilyl)silyl radical is effective in isomerizing some (Z)-olefins into their thermodynamically more stable (E)-isomers by an addition-elimination path.

引用

页码：5147 / 5150

页数：4

共 18 条

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