Pure rotational spectrum of HCl and DCl in liquid SF6

被引：56

作者：

Birnbaum, George ^{[1
]}

Ho, W. ^{[1
]}

机构：

[1] N Amer Rockwell Co, Ctr Sci, Thousand Oaks, CA USA

来源：

CHEMICAL PHYSICS LETTERS | 1970年 / 5卷 / 06期

关键词：

D O I：

10.1016/0009-2614(70)85158-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The far infrared spectrum of dilute solutions of HCl and DCl dissolved in liquid SF6 at 0 degrees C is observed in the frequency region 30 cm(-1) to 230 cm(-1). A broad absorption band is obtained for DCl which is in excellent agreement with the band envelope defined by the relative integrated intensity of each of the pure rotational transitions in the gas phase. The HCl spectrum. however. shows clearly resolved lines superimposed on a broad absorption band. These lines are readily identifiable with the pure rotational lines in the gas phase.

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页码：334 / 336

页数：3

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