SOLVENT EXTRACTION OF SOME METAL IONS WITH P-T-BUTYLCALIX[6]ARENE

被引：5

作者：

Masuda, Yoshitaka ^{[1
]}

Sawano, Tetuva ^{[1
]}

Sekido, Eiichi ^{[1
]}

机构：

[1] Kobe Univ, Fac Sci, Dept Chem, Nada Ku, Kobe, Hyogo 657, Japan

来源：

ANALYTICAL SCIENCES | 1991年 / 7卷

关键词：

silver; palladium; nickel; solvent extraction; p-t-butylaclix[6]arene;

D O I：

10.2116/analsci.7.Supple_31

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Hexameric p-t-butylcalix[6]arene(tbca,H,L,m=2 or 1) in the various solvents has shown an ability to extract silver(I), palladium(II) and nickel(11) from the ammonia alkaline solution. The results from liquid liquid extraction study suggested the formation of the 1:1 metal (Ag, Pd and Ni) to tbca complex as the extracted species. A percent extraction (% E) pattern of Pd(11)>Ni(11)>Ag(1) was obtained in 1,2-dichloroethane, dichloromethane and nitrobenzene solvents. The order of high extractability (pH=11.7 and pH=13.5) corresponds to increase of dielectric constant except nitrobenzene.

引用

页码：31 / 34

页数：4

共 11 条

[1] CESIUM-SELECTIVE POLY(VINYL CHLORIDE) MEMBRANE ELECTRODES BASED ON CALIX[6]ARENE ESTERS [J].

CADOGAN, A ;

DIAMOND, D ;

SMYTH, MR ;

SVEHLA, G ;

MCKERVEY, MA ;

SEWARD, EM ;

HARRIS, SJ .

ANALYST, 1990, 115 (09) :1207-1210

[2]

DHAWAN B, 1987, MAKROMOL CHEM, V188, P921

[3] A SODIUM ION-SELECTIVE ELECTRODE BASED ON METHYL PARA-TERT-BUTYLCALIX[4]ARYL ACETATE AS THE IONOPHORE [J].

DIAMOND, D ;

SVEHLA, G ;

SEWARD, EM ;

MCKERVEY, MA .

ANALYTICA CHIMICA ACTA, 1988, 204 (1-2) :223-231

[4]

Gutsche C.D., 1989, CALIXARENE

[5] SELECTIVE M+-H+ COUPLED TRANSPORT OF CATIONS THROUGH A LIQUID MEMBRANE BY MACROCYCLIC CALIXARENE LIGANDS [J].

IZATT, RM ;

LAMB, JD ;

HAWKINS, RT ;

BROWN, PR ;

IZATT, SR ;

CHRISTENSEN, JJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (07) :1782-1785

[6] CATION-TRANSPORT FROM MULTIPLE ALKALI CATION MIXTURES USING A LIQUID MEMBRANE SYSTEM CONTAINING A SERIES OF CALIXARENE CARRIERS [J].

IZATT, SR ;

HAWKINS, RT ;

CHRISTENSEN, JJ ;

IZATT, RM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (01) :63-66

[7] POLYMERIC MEMBRANE SODIUM-SELECTIVE ELECTRODES BASED ON LIPOPHILIC CALIX[4]ARENE DERIVATIVES [J].

KIMURA, K ;

MIURA, T ;

MATSUO, M ;

SHONO, T .

ANALYTICAL CHEMISTRY, 1990, 62 (14) :1510-1513

[8] LIPOPHILIC CROWN-4 DERIVATIVES AS LITHIUM IONOPHORES [J].

KITAZAWA, S ;

KIMURA, K ;

YANO, H ;

SHONO, T .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (23) :6978-6983

[9]

Lutz M., 1986, AUST J CHEM, V41, P1465

[10] MOLECULAR DESIGN OF CALIXARENE-BASED URANOPHILES WHICH EXHIBIT REMARKABLY HIGH-STABILITY AND SELECTIVITY [J].

SHINKAI, S ;

KOREISHI, H ;

UEDA, K ;

ARIMURA, T ;

MANABE, O .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (21) :6371-6376

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