A CONVENIENT SYNTHESIS OF DIAMINOGLYOXIME AND DIAMINOFURAZAN - USEFUL PRECURSORS FOR THE SYNTHESIS OF HIGH-DENSITY ENERGETIC MATERIALS

被引：62

作者：

GUNASEKARAN, A

JAYACHANDRAN, T

BOYER, JH

TRUDELL, ML

机构：

[1] Department of Chemistry, University of New Orleans, New Orleans, Louisiana

来源：

JOURNAL OF HETEROCYCLIC CHEMISTRY | 1995年 / 32卷 / 04期

关键词：

D O I：

10.1002/jhet.5570320452

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reaction of glyoxime (4) and hydroxylamine hydrochloride in aqueous sodium hydroxide was found to be a safe and inexpensive method for the preparation of multigram quantities of diaminoglyoxime (5). Potassium hydroxide mediated dehydration of 5 furnished diaminofurazan (1) in good yield of exceptional purity. The ready availability of 1 and 5 has facilitated the synthesis of new energetic furazan derivative 8.

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页码：1405 / 1407

页数：3

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