THE STRUCTURE OF LAUROBTUSOL, A NEW REARRANGED SESQUITERPENOID FROM THE MEDITERRANEAN RED ALGA LAURENCIA-OBTUSA

被引:7
作者
CACCAMESE, S [1 ]
AMICO, V [1 ]
NERI, P [1 ]
FOTI, M [1 ]
机构
[1] CNR,IST SONTANZE NAT,I-95028 VALVERDE,ITALY
关键词
D O I
10.1016/S0040-4020(01)96059-4
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
An alcohol with a new tricyclic humulane skeleton, laurobtusol, was isolated from the Mediterranean Red Alga Laurencia obtusa. The structure was established mainly by 2 D NMR methods and the relative configuration was assigned by a quantiative computer simulation of the lanthanide induced shifts in the H-1 NMR spectrum and Molecular Mechanics calculation (MM2).
引用
收藏
页码:10101 / 10108
页数:8
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