EVIDENCE OF REACTING IODINE SPECIES AT THE SURFACE OF A POLYPHENYLACETYLENE FILM INVESTIGATED BY XPS

被引：22

作者：

POLZONETTI, G ^{[1
]}

FURLANI, A ^{[1
]}

RUSSO, MV ^{[1
]}

CAMUS, AM ^{[1
]}

MARSICH, N ^{[1
]}

机构：

[1] UNIV TRIESTE,DEPT CHEM SCI,I-34127 TRIESTE,ITALY

来源：

JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA | 1990年 / 52卷

关键词：

D O I：

10.1016/0368-2048(90)85049-F

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

The reaction of iodine vapours on a polyphenylacetylene thin film is investigated. XPS measurements give evidence for a mechanism leading to the formation of very stable (up to 250°C under U.H.V.) 15t- poliiodidc. The dopant species is homogeneously dispersed at the surface, but does not penetrate in the bulk. IR spectra suggest modifications of the polymer structure and formation of charged defects upon doping. © 1990.

引用

收藏

页码：581 / 588

页数：8

相关论文

共 34 条

[21] POLYMERIZATIONS OF ACETYLENES AND CYCLIC OLEFINS INDUCED BY METAL CARBYNES [J].

KATZ, TJ ;

HO, TH ;

SHIH, NY ;

YING, YC ;

STUART, VIW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (09) :2659-2668

[22] ALCL3-ASSISTED FORMATION OF CHARGE-TRANSFER COMPLEXES BETWEEN POLYACETYLENE AND TETRACYANOETHYLENE, TCNE [J].

KULSZEWICZBAJER, I ;

BILLAUD, D .

SYNTHETIC METALS, 1988, 22 (03) :239-245

[23] POLYMERIZATION OF PHENYLACETYLENES .15. COPOLYMERIZATION OF PHENYLACETYLENE WITH VARIOUS ACETYLENES BY W-BASED AND MO-BASED CATALYSTS [J].

MASUDA, T ;

YOSHIZAWA, T ;

OKANO, Y ;

HIGASHIMURA, T .

POLYMER, 1984, 25 (04) :503-506

[24] TEMPERATURE AND FIELD-DEPENDENCE OF ELECTRON CURRENTS IN FILMS OF TRANS-POLYPHENYLACETYLENE [J].

OGALE, K ;

WILSON, ML ;

EHRLICH, P .

POLYMER, 1987, 28 (04) :587-592

[25] COMBINED ESCA AND AUGER SPECTROMETER [J].

PALMBERG, PW .

JOURNAL OF VACUUM SCIENCE & TECHNOLOGY, 1975, 12 (01) :379-384

[26] PROPERTIES OF IODINE COMPLEXES OF MONOSUBSTITUTED POLYACETYLENES [J].

PETIT, MA ;

SOUM, AH ;

LECLERC, M ;

PRUDHOMME, RE .

JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 1987, 25 (02) :423-433

[27] X-RAY PHOTOELECTRON-SPECTROSCOPY OF IODINE-DOPED POLYETHYNYLFERROCENE [J].

POLZONETTI, G ;

FARUFFINI, V ;

FURLANI, A ;

RUSSO, MV .

SYNTHETIC METALS, 1988, 25 (04) :375-384

[28]

PORTE L, 1976, B SOC CHIM FR, V7, P1013

[29] ELECTRICAL-PROPERTIES OF POLYMERS PREPARED FROM IODO-(4-NITROPHENYL)ACETYLENE [J].

ROTTI, M ;

KRIKOR, H ;

NAGELS, P .

SYNTHETIC METALS, 1987, 21 (03) :343-352

[30] PHOTOELECTRON-SPECTROSCOPY OF IODINE-DOPED POLYACETYLENE [J].

SALANECK, WR ;

THOMAS, HR ;

BIGELOW, RW ;

DUKE, CB ;

PLUMMER, EW ;

HEEGER, AJ ;

MACDIARMID, AG .

JOURNAL OF CHEMICAL PHYSICS, 1980, 72 (06) :3674-3678

← 1 2 3 4 →