THE 1ST PALLADIUM(0) COMPLEX WITH ONLY SECONDARY PHOSPHINES AS LIGANDS AND ITS OXIDATIVE-ADDITION REACTIONS WITH CH2CL2 AND CHCL3, GIVING THE THERMALLY STABLE DERIVATIVES TRANS-[PDCL(R)(PBU(T)2H)2] (R = CH2CL, CHCL2)

被引：53

作者：

LEONI, P ^{[1
]}

机构：

[1] SCUOLA NORMALE SUPER PISA,I-56100 PISA,ITALY

来源：

ORGANOMETALLICS | 1993年 / 12卷 / 07期

关键词：

D O I：

10.1021/om00031a012

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Pd(PBut2H)3, obtained by reacting Pd-(eta5-C5H5)(eta3-C3H5) With PBut2H, oxidatively adds the C-Cl bond of methylene chloride and of chloroform, giving the thermally stable derivatives trans-[PdCl(CH2Cl)(PBut2H)2], (2) and trans-[PdCl(CHCl2)(PBut2H)2], (3), respectively. Complex 1 solutions deposit, by gentle warming, the known dimer [Pd(mu-PBut2)(PBut2H)]2.

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页码：2432 / 2434

页数：3

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