THE 1ST PALLADIUM(0) COMPLEX WITH ONLY SECONDARY PHOSPHINES AS LIGANDS AND ITS OXIDATIVE-ADDITION REACTIONS WITH CH2CL2 AND CHCL3, GIVING THE THERMALLY STABLE DERIVATIVES TRANS-[PDCL(R)(PBU(T)2H)2] (R = CH2CL, CHCL2)

被引：53

作者：

LEONI, P ^{[1
]}

机构：

[1] SCUOLA NORMALE SUPER PISA,I-56100 PISA,ITALY

来源：

ORGANOMETALLICS | 1993年 / 12卷 / 07期

关键词：

D O I：

10.1021/om00031a012

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Pd(PBut2H)3, obtained by reacting Pd-(eta5-C5H5)(eta3-C3H5) With PBut2H, oxidatively adds the C-Cl bond of methylene chloride and of chloroform, giving the thermally stable derivatives trans-[PdCl(CH2Cl)(PBut2H)2], (2) and trans-[PdCl(CHCl2)(PBut2H)2], (3), respectively. Complex 1 solutions deposit, by gentle warming, the known dimer [Pd(mu-PBut2)(PBut2H)]2.

引用

收藏

页码：2432 / 2434

页数：3

相关论文

共 53 条

[31] SYNTHESIS OF BINUCLEAR PLATINUM(IV) COMPLEXES WITH PT(CH2)NPT UNITS [J].

MONAGHAN, PK ;

PUDDEPHATT, RJ .

ORGANOMETALLICS, 1985, 4 (08) :1406-1412

[32] REACTIONS OF CROWDED SECONDARY PHOSPHINES WITH (ETA-3-2-XC3H4)M(1,5-COD) (X = H OR ME AND M = RH OR IR) [J].

MURRAY, BD ;

POWER, PP .

ORGANOMETALLICS, 1984, 3 (08) :1199-1204

[33] PALLADIUM-CATALYZED OR NICKEL-CATALYZED CROSS COUPLING - A NEW SELECTIVE METHOD FOR CARBON CARBON BOND FORMATION [J].

NEGISHI, EI .

ACCOUNTS OF CHEMICAL RESEARCH, 1982, 15 (11) :340-348

[34] OXIDATIVE-ADDITION REACTIONS OF ALKYL CHLORIDES WITH CHLOROBIS(CYCLOOCTENE)RHODIUM(I) AND THE BIS(OXAZOLINYL)PYRIDINE LIGAND - FORMATION OF STABLE (CHLOROMETHYL)RHODIUM(III) COMPLEXES AND THEIR REACTIONS [J].

NISHIYAMA, H ;

HORIHATA, M ;

HIRAI, T ;

WAKAMATSU, S ;

ITOH, K .

ORGANOMETALLICS, 1991, 10 (08) :2706-2708

[35] H-1 AND P-31 NMR SPECTRAL-ANALYSIS OF THE CIS-TRANS EQUILIBRIA OF [NIX2(CY2PH)2] COMPLEXES - [AMY2]2 SPIN SYSTEMS [J].

PALMER, RA ;

WHITCOMB, DR .

JOURNAL OF MAGNETIC RESONANCE, 1980, 39 (03) :371-379

[36] STUDIES ON REACTIVITY OF METAL PI-COMPLEXES .11. DETECTION OF PI-SIGMA REARRANGEMENTS IN LIGAND DISPLACEMENT-REACTIONS OF PI ALLYL PI CYCLOPENTADIENYL PALLADIUM COMPLEXES [J].

PARKER, G ;

WERNER, H .

HELVETICA CHIMICA ACTA, 1973, 56 (08) :2819-2826

[37]

PASQUALI M, IN PRESS GAZZ CHIM I

[38] SEQUENTIAL SYNTHESIS OF FEPT, FEPT2, AND FEPT3 COMPLEXES FROM THE REACTION OF FE(CO)4(PR2H) WITH PT(C2H4)2(PCY3) - A DETAILED LOOK AT A CLUSTER ASSEMBLY PROCESS [J].

POWELL, J ;

GREGG, MR ;

SAWYER, JF .

INORGANIC CHEMISTRY, 1988, 27 (25) :4526-4528

[39] SYNTHESIS OF PTRU2 AND PTRU3 HETEROMETALLIC COMPLEXES FROM THE REACTION OF RU3(CO)11(PPH2H) WITH ZEROVALENT COMPLEXES OF PLATINUM - SINGLE-CRYSTAL X-RAY-DIFFRACTION STUDIES OF PTRU2(MU-PPH2)(MU-H)(CO)7(PCY3) AND PTRU3(MU-PPH2)(MU-H)(CO)9(PCY3) [J].

POWELL, J ;

BREWER, JC ;

GULIA, G ;

SAWYER, JF .

INORGANIC CHEMISTRY, 1989, 28 (25) :4470-4476

[40] PREPARATION AND CRYSTAL-STRUCTURE OF THE 1ST PHOSPHIDO-BRIDGED GOLD(I) COMPLEX - TETRA(NORMAL-BUTYL)AMMONIUM DIPHENYLPHOSPHIDOBIS[BROMOGOLD(I)] [J].

PRITCHARD, RG ;

DYSON, DB ;

PARISH, RV ;

MCAULIFFE, CA ;

BEAGLEY, B .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (05) :371-372

← 1 2 3 4 5 6 →