A SUGGESTION TO THE PPL ACTIVE-SITE MODEL DILEMMA

被引：37

作者：

WIMMER, Z

机构：

[1] Institute of Organic Chemistry and Biochemistry ČAV, CS-166 10 Prague 6

来源：

TETRAHEDRON | 1992年 / 48卷 / 39期

关键词：

ACETATE HYDROLYSIS; PPL ACTIVE SITE MODEL; PREDICTING OF STEREOCHEMISTRY;

D O I：

10.1016/S0040-4020(01)86591-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A PPL active site model with a new explanation of the nature of the hydrophobic and hydrophilic substituents of the chiral centre predicted of the PPL-mediated hydrolysis products is discussed using several examples given by the literature data, and those obtained in our research. A comparison with other PPL active site models built recently is given as well.

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收藏

页码：8431 / 8436

页数：6

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