A DIFUNCTIONAL RECEPTOR FOR THE SIMULTANEOUS COMPLEXATION OF ANIONS AND CATIONS - RECOGNITION OF KH2PO4

被引：131

作者：

RUDKEVICH, DM

BRZOZKA, Z

PALYS, M

VISSER, HC

VERBOOM, W

REINHOUDT, DN

机构：

[1] UNIV TWENTE,ORGAN CHEM LAB,7500 AE ENSCHEDE,NETHERLANDS

[2] TECH UNIV WARSAW,DEPT ANALYT CHEM,WARSAW,POLAND

[3] UNIV WARSAW,DEPT CHEM,WARSAW,POLAND

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 04期

关键词：

D O I：

10.1002/anie.199404671

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The Lewis acidic uranyl center and the amide units of receptor 1 bind the anion of the hydrophilic, biologically relevant salt KH2PO4 specifically, and simultaneously the crown ether units bind the cation. The complexation properties of 1 were studied with NMR spectroscopy, mass spectrometry, and cyclic voltammetry. The recognition demonstrated for this simple salt could be of great importance for membrane transport, extraction, and sensor technology. (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：467 / 468

页数：2

共 27 条

[1] NEW POCKET IONOPHORES WITH POTENTIAL FOR SIMULTANEOUS CHELATION OF ANIONS AND CATIONS - SYNTHESIS AND SCOPE OF CHELATING PROPERTIES
ARAFA, EA
KINNEAR, KI
LOCKHART, JC
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (01) : 61 - 64
[2] MACROCYCLES CONTAINING TIN - PREPARATION OF MACROBICYCLIC LEWIS ACIDIC HOSTS CONTAINING 2 TIN ATOMS AND SN-119 NMR-STUDIES OF THEIR CHLORIDE AND BROMIDE BINDING-PROPERTIES IN SOLUTION
BLANDA, MT
HORNER, JH
NEWCOMB, M
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1989, 54 (19) : 4626 - 4636
[3] THE DESIGN OF MOLECULAR HOSTS, GUESTS, AND THEIR COMPLEXES (NOBEL LECTURE)
CRAM, DJ
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1988, 27 (08): : 1009 - 1020
[4] CRAM DJ, 1988, ANGEW CHEM, V100, P1041, DOI DOI 10.1002/ANGE.19881000804
[5] DEJONG F, 1981, STABILITY REACTIVITY
[6] A NOVEL RECEPTOR FOR DICARBOXYLIC-ACID DERIVATIVES
FLACK, SS
CHAUMETTE, JL
KILBURN, JD
LANGLEY, GJ
WEBSTER, M
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (04) : 399 - 401
[7] MACROCYCLIC LIGANDS EXAMINED BY FAST ATOM BOMBARDMENT MASS-SPECTROMETRY - DIRECT OBSERVATION OF METAL CATION SELECTIVITY IN COMPLEXATION
JOHNSTONE, RAW
ROSE, ME
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1983, (21) : 1268 - 1270
[8] FAST ATOM BOMBARDMENT OF CROWN ETHER CATION COMPLEXES IN SOLUTION - INFERENCES ON MECHANISMS OF ENERGY-TRANSFER
JOHNSTONE, RAW
LEWIS, IAS
ROSE, ME
[J]. TETRAHEDRON, 1983, 39 (09) : 1597 - 1603
[9] SYNTHESIS AND TRANSPORT-PROPERTIES OF 12-SILACROWN-3, A NEW TYPE OF ANION COMPLEXING AGENT
JUNG, ME
XIA, HJ
[J]. TETRAHEDRON LETTERS, 1988, 29 (03) : 297 - 300
[10] 1,8-ANTHRACENEDIETHYNYLBIS(CATECHOL BORONATE) - A BIDENTATE LEWIS ACID ON A NOVEL FRAMEWORK
KATZ, HE
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1989, 54 (09) : 2179 - 2183

← 1 2 3 →