SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF 2 NOVEL GD-III BETA-DIKETONATES [GD-4(MU(3)-OH)(4)(MU(2)-H2O)(2)(H2O)(4)(HFPD)(8)]CENTER-DOT-2C(6)H(6)CENTER-DOT-H2O 1 AND [GD(HFPD)(3)(ME(2)CO)(H2O)]2 (HFPD-H=1,1,1,5,5,5-HEXAFLUOROPENTANE-2,4-DIONE)

被引：55

作者：

PLAKATOURAS, JC ^{[1
]}

BAXTER, I ^{[1
]}

HURSTHOUSE, MB ^{[1
]}

MALIK, KMA ^{[1
]}

MCALEESE, J ^{[1
]}

DRAKE, SR ^{[1
]}

机构：

[1] UNIV WALES COLL CARDIFF,DEPT CHEM,CARDIFF CF1 3TB,S GLAM,WALES

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 21期

关键词：

D O I：

10.1039/c39940002455

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two novel Gd-III-hfpd complexes 1 and 2 have been synthesised from aqueous and non-aqueous media; the crystal structural studies reveal that 1 has a M(4)O(6) bicapped cubane core with the metals having tricapped trigonal prismatic geometry, while 2 is a monomeric adduct with water and acetone in the coordination sphere, with:the metal having square antiprismatic geometry.

引用

页码：2455 / 2456

页数：2

共 16 条

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