SUBSTITUTED 4A-METHYLOCTAHYDROPHENANTRENES - CONFORMATION AND PROTON MAGNETIC-RESONANCE CHARACTERISTICS

被引:16
作者
CAMPBELL, AL [1 ]
LEADER, HN [1 ]
SIERRA, MG [1 ]
SPENCER, CL [1 ]
MCCHESNEY, JD [1 ]
机构
[1] UNIV KANSAS,SCH PHARM,DEPT MED CHEM,LAWRENCE,KS 66045
关键词
D O I
10.1021/jo01329a032
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Analysis of the 1H NMR resonance position of the 4a-methyl group of substituted 4a-methyloctahydro-phenanthrenes allows an assignment of conformation of the overall ring system. With a series of reference positions established, it is possible to assign tentative stereochemistry to substituents in newly prepared or isolated substances. © 1979, American Chemical Society. All rights reserved.
引用
收藏
页码:2755 / 2757
页数:3
相关论文
共 25 条
[1]   MOLECULAR ORBITAL APPROACH TO MECHANISM OF ELECTROPHILIC ADDITIONS TO OLEFINS [J].
BACH, RD ;
HENNEIKE, HF .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1970, 92 (19) :5589-&
[2]   STEREOSELECTIVE SYNTHESIS OF 4A-METHYLOCTAHYDROPHENANTHRENES - NOVEL-APPROACH .1. C-2 AND C-3 SUBSTITUTED SERIES [J].
CAMPBELL, AL ;
LEADER, HN ;
SPENCER, CL ;
MCCHESNEY, JD .
JOURNAL OF ORGANIC CHEMISTRY, 1979, 44 (15) :2746-2754
[3]  
CAMPBELL AL, 1978, THESIS U KANSAS
[4]  
CAPOZZI G, 1975, TETRAHEDRON LETT, P2603
[5]  
CHANG WK, 1978, J ORG CHEM, V43, P1904
[6]  
DUBOIS JE, 1972, CR ACAD SCI C CHIM, V274, P1130
[7]  
DUBOIS JE, 1968, B SOC CHIM FR, P2094
[8]  
DUBOIS JE, 1965, TETRAHEDRON LETT, P1629
[9]   RELATION BETWEEN TOPOLOGY AND NU(C=0) FREQUENCY IN SATURATED ALIPHATIC KETONES .2. PROPERTIES IN VAPOR PHASE AND RELATION OF TOPOLOGICAL DATA [J].
DUBOIS, JE ;
MASSAT, A ;
GUILLAUME, P .
JOURNAL OF MOLECULAR STRUCTURE, 1969, 4 (5-6) :403-+
[10]  
DUBOIS JE, 1978, TETRAHEDRON LETT, P4099