共 13 条
ON THE LINEARIZATION PROBLEM OF THE BENT CHAIN IN AMORPHOUS POLYCARBONATE
被引:14
作者:
CERVINKA, L
[1
]
FISCHER, EW
[1
]
DETTENMAIER, M
[1
]
机构:
[1] MAX PLANCK INST POLYMER RES, W-6500 MAINZ, GERMANY
来源:
关键词:
INTERMOLECULAR ORDER;
POLYCARBONATE;
NEUTRON SCATTERING;
CRYSTALLINE STRUCTURE;
D O I:
10.1016/0032-3861(91)90555-W
中图分类号:
O63 [高分子化学(高聚物)];
学科分类号:
070305 ;
080501 ;
081704 ;
摘要:
The linearization problem of the bent (banana-like) polycarbonate chain is solved and two linear chains are found that differ in alteration of trans and cis conformations. Calculation of neutron scattering curves from ordered (crystalline-like) regions with linear and bent chains in different arrangements and comparison with experimental scattering curves exclude the existence of linear chains and of crystalline-like ordering in amorphous polycarbonate.
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页码:12 / 18
页数:7
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