NITRO DISPLACEMENT BY METHANETHIOL ANION - SYNTHESIS OF BIS(METHYLTHIO)BENZOIC, TRIS(METHYLTHIO)BENZOIC, TETRAKIS(METHYLTHIO)BENZOIC, AND PENTAKIS(METHYLTHIO)BENZOIC ACIDS AND RELATED DERIVATIVES

被引：12

作者：

BECK, JR

YAHNER, JA

机构：

[1] Lilly Research Laboratories, Division of Eli Lilly &Company, Greenfield

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1978年 / 43卷 / 10期

关键词：

D O I：

10.1021/jo00404a047

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

3,4,5-Tris(methylthio)benzamide has been synthesized by a process involving nitro displacement with methanethiol anion. Similarly prepared were various bis-, tris-, and tetrakis(methylthio)benzoic acids and their S-methyl thioesters. Several of the thioethers were oxidized to the corresponding sulfones. Also prepared were 3,4,5-tris(methylthio)benzenesulfonamide, 3,4,5-tris(methylthio)phenylacetamide, and pentakis(methylthio)benzamide. © 1978, American Chemical Society. All rights reserved.

引用

页码：2052 / 2055

页数：4

共 5 条

[1] DIRECT SYNTHESIS OF BENZO[B]THIOPHENE-2-CARBOXYLATE ESTERS INVOLVING NITRO DISPLACEMENT [J].