EXCITED-STATE PROPERTIES OF LAMELLAR SOLIDS DERIVED FROM METAL-COMPLEXES AND HYDROGEN URANYL PHOSPHATE

被引：12

作者：

HUNSBERGER, LR ^{[1
]}

ELLIS, AB ^{[1
]}

机构：

[1] UNIV WISCONSIN,DEPT CHEM,MADISON,WI 53706

来源：

COORDINATION CHEMISTRY REVIEWS | 1990年 / 97卷

关键词：

D O I：

10.1016/0010-8545(90)80090-G

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Hydrogen uranyl phosphate (HUP), HUO2PO4·4H2O, is a layered solid that undergoes intercalative ion-exchange reactions with guest cationic species spanning the periodic table. The host lattice exhibits highly efficient green photoluminescence (PL) characteristic of the uranyl (UO22+ moiety. Structural and optical perturbations of the host and guest generally accompany intercalation reactions. Guest metal complexes have afforded an opportunity to study host-to-guest energy transfer, interlamellar acid-base/precipitation chemistry, interlamellar redox chemistry, and host lattice substitution chemistry. These reactions are summarized in this article. © 1990.

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页码：209 / 224

页数：16

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