INFLUENCE OF GALACTOMANNAN ON THE STRUCTURE AND THERMAL-BEHAVIOR OF XANTHAN GALACTOMANNAN MIXTURES

被引:29
作者
FERNANDES, PB [1 ]
机构
[1] UNIV CATOL PORTUGUESA, ESCOLA SUPER BIOTECNOL, P-4200 Porto, PORTUGAL
关键词
D O I
10.1016/0260-8774(94)P2647-N
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Mixed gels of xanthan gum and galactomannans (guar, whole and fractionated locust bean gum - LBG) were compared by means of oscillatory shear measurements. Whatever the LBG fraction, a synergistic maximum was observed when the ratio of xanthan to galactomannan was 1 : 1. However, the magnitude of this maximum varied with the LBG fraction used. The thermal behaviour of 1 : 1 xanthan/LBF fractions was characterized by cooling-heating cycles. A slight thermal hysteresis was systematically described for the several xanthan/LBG fraction systems. It was observed that the mannose to galactose (M/G) ratio of LBG fractions determined the sol-gel transition (gelation and melting temperature) of the xanthan/galactomannan mixed systems. From the galactomannan fine structure and thermorheological profiles it is evident that the higher the M/G ratio of galactomannan samples, the higher is the synergistic interaction as is also the transition temperature of the xanthan/LBG systems.
引用
收藏
页码:269 / 283
页数:15
相关论文
共 48 条
[1]  
ANDERSON DMW, 1986, FOOD ADDIT CONTAM, V3, P231
[2]   A SIMPLE AND RAPID PREPARATION OF ALDITOL ACETATES FOR MONOSACCHARIDE ANALYSIS [J].
BLAKENEY, AB ;
HARRIS, PJ ;
HENRY, RJ ;
STONE, BA .
CARBOHYDRATE RESEARCH, 1983, 113 (02) :291-299
[3]   Comparative studies of the mechanical properties of mixed gels formed by kappa carrageenan and tara gum or carob gum [J].
Cairns, P. ;
Morris, V. J. ;
Miles, M. J. ;
Brownsey, G. J. .
FOOD HYDROCOLLOIDS, 1986, 1 (01) :89-93
[4]   X-RAY FIBER-DIFFRACTION STUDIES OF SYNERGISTIC, BINARY POLYSACCHARIDE GELS [J].
CAIRNS, P ;
MILES, MJ ;
MORRIS, VJ ;
BROWNSEY, GJ .
CARBOHYDRATE RESEARCH, 1987, 160 :411-423
[5]   CONFORMATIONAL ASPECTS OF XANTHAN-GALACTOMANNAN GELATION [J].
CHEETHAM, NWH ;
MASHIMBA, ENM .
CARBOHYDRATE POLYMERS, 1988, 9 (03) :195-212
[6]  
CLARK AH, 1987, ADV POLYM SCI, V83, P57
[7]   CONCENTRATION REGIMES IN XANTHAN GUM SOLUTIONS DEDUCED FROM FLOW AND VISCOELASTIC PROPERTIES [J].
CUVELIER, G ;
LAUNAY, B .
CARBOHYDRATE POLYMERS, 1986, 6 (05) :321-333
[8]   XANTHAN CAROB INTERACTIONS AT VERY LOW CONCENTRATION [J].
CUVELIER, G ;
LAUNAY, B .
CARBOHYDRATE POLYMERS, 1988, 8 (04) :271-284
[9]   FREQUENCY-DEPENDENCE OF VISCOELASTIC PROPERTIES OF SOME PHYSICAL GELS NEAR THE GEL POINT [J].
CUVELIER, G ;
LAUNAY, B .
MAKROMOLEKULARE CHEMIE-MACROMOLECULAR SYMPOSIA, 1990, 40 :23-31
[10]  
Cuvelier G., 1985, GUMS STABILISERS FOO, V3, P147