H-1 NMR-STUDY OF CONVERSION OF 13(S)-HYDROPEROXY LINOLEIC-ACID BY SOYA BEAN LIPOXYGENASE-I

被引：5

作者：

EGMOND, MR

WILLIAMS, RJP

机构：

[1] Inorganic Chemistry Laboratory, Oxford, 0X1 3QR, South Parks Road

来源：

BIOCHIMICA ET BIOPHYSICA ACTA | 1978年 / 531卷 / 02期

关键词：

D O I：

10.1016/0005-2760(78)90137-6

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

The conversion of 13(S)-hydroperoxy linoleic acid by lipoxygenase I at 298 K was monitored by 1H NMR and ultraviolet absorption spectroscopy. The rate constant for the conversion of the hydroperoxide, k = 45.8 ± 7.5 M-1 · s-1, depends on the concentrations of both enzyme and hydroperoxide. This constant is not affected by O2, nor by solvent isotope effects. © 1978.

引用

页码：141 / 148

页数：8

共 24 条

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