The magnetic and spectral properties of the DI-mu-chlorobis[ trichlorocuprate (II)] anion, [Cu(2)Cl(8)](4-)

被引：22

作者：

Barnes, J. A. ^{[1
]}

Hatfield, W. E. ^{[1
]}

Hodgson, D. J. ^{[1
]}

机构：

[1] Univ N Carolina, Dept Chem, Chapel Hill, NC 27514 USA

来源：

CHEMICAL PHYSICS LETTERS | 1970年 / 7卷 / 03期

关键词：

D O I：

10.1016/0009-2614(70)80187-7

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The magnetic susceptibility of [Co(en)(3)](2)[Cu(2)CI(8)] Cl(2)center dot 2H(2)O exhibits an antiferromagnetic transition near 15.5 degrees K. Spin coupling is confirmed by EPR measurements. The near infrared spectrum of the complex is also reported.

引用

页码：374 / 376

页数：3

共 15 条

[1] ANOMALOUS PARAMAGNETISM OF COPPER ACETATE
BLEANEY, B
BOWERS, KD
[J]. PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1952, 214 (1119): : 451 - 465
[2] Figgis B., 1960, MODERN COORDINATION, P403
[3] MAGNETIC STUDIES WITH COPPER(II) SALTS .1. ANOMALOUS PARAMAGNETISM AND DELTA-BONDING IN ANHYDROUS AND HYDRATED COPPER(II) ACETATES
FIGGIS, BN
MARTIN, RL
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1956, (OCT): : 3837 - 3846
[4] VERSATILE AND SENSITIVE VIBRATING-SAMPLE MAGNETOMETER
FONER, S
[J]. REVIEW OF SCIENTIFIC INSTRUMENTS, 1959, 30 (07) : 548 - 557
[5] GOODENOUGH JB, 1963, MAGNETISM CHEM BOND, P180
[6] SPIN-SPIN COUPLING IN BINUCLEAR COMPLEXES
HATFIELD, WE
PASCHAL, JS
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1964, 86 (18) : 3888 - &
[7] SPECTRAL + MAGNETIC PROPERTIES OF CHLOROCUPRATES
HATFIELD, WE
PIPER, TS
[J]. INORGANIC CHEMISTRY, 1964, 3 (06) : 841 - &
[8] SPIN-SPIN COUPLING IN BINUCLEAR COMPLEXES .3. MAGNETIC PROPERTIES OF COPPER SALTS OF SUBSTITUTED BENZOIC ACIDS
HATFIELD, WE
FOUNTAIN, CS
WHYMAN, R
[J]. INORGANIC CHEMISTRY, 1966, 5 (11) : 1855 - &
[9] HATFIELD WE, IN PRESS
[10] HODGSON DJ, 1970, CHEM COMMUN, P786

← 1 2 →