The magnetic and spectral properties of the DI-mu-chlorobis[ trichlorocuprate (II)] anion, [Cu(2)Cl(8)](4-)

被引:22
作者
Barnes, J. A. [1 ]
Hatfield, W. E. [1 ]
Hodgson, D. J. [1 ]
机构
[1] Univ N Carolina, Dept Chem, Chapel Hill, NC 27514 USA
关键词
D O I
10.1016/0009-2614(70)80187-7
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The magnetic susceptibility of [Co(en)(3)](2)[Cu(2)CI(8)] Cl(2)center dot 2H(2)O exhibits an antiferromagnetic transition near 15.5 degrees K. Spin coupling is confirmed by EPR measurements. The near infrared spectrum of the complex is also reported.
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页码:374 / 376
页数:3
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