The magnetic and spectral properties of the DI-mu-chlorobis[ trichlorocuprate (II)] anion, [Cu(2)Cl(8)](4-)

被引：22

作者：

Barnes, J. A. ^{[1
]}

Hatfield, W. E. ^{[1
]}

Hodgson, D. J. ^{[1
]}

机构：

[1] Univ N Carolina, Dept Chem, Chapel Hill, NC 27514 USA

来源：

CHEMICAL PHYSICS LETTERS | 1970年 / 7卷 / 03期

关键词：

D O I：

10.1016/0009-2614(70)80187-7

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The magnetic susceptibility of [Co(en)(3)](2)[Cu(2)CI(8)] Cl(2)center dot 2H(2)O exhibits an antiferromagnetic transition near 15.5 degrees K. Spin coupling is confirmed by EPR measurements. The near infrared spectrum of the complex is also reported.

引用

页码：374 / 376

页数：3

共 15 条

[11] KONIG E, 1966, MAGNETIC PROPERTIES, P2
[12] KURNAKOW NS, 1893, Z ANORG CHEM, V17, P225
[13] MARTIN RL, 1968, NEW PATHWAYS INORGAN, P184
[14] GEOMETRY AND STABILIZATION OF NI2CL84- ANION IN HN(C2H4)3NCH3NICL4)2
ROSS, FK
STUCKY, GD
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1970, 92 (15) : 4538 - &
[15] SPIN-SPIN COUPLING IN BINUCLEAR COMPLEXES .4. SUBSTITUTED HETEROCYCLIC N-OXIDE COMPLEXES OF COPPER(2) HALIDES .3. MAGNETIC AND SPECTRAL PROPERTIES OF COMPLEXES WITH SUBSTITUTED QUINOLINE N-OXIDES
WHYMAN, R
COPLEY, DB
HATFIELD, WE
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1967, 89 (13) : 3135 - &

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