A NEW TYPE OF STRUCTURE IN SODIUM AMIDE RING CHEMISTRY - CRYSTAL-STRUCTURE OF [PHCH2(ME)NNA(TMEDA)]2 SHOWING A BUCKLED, RATHER THAN THE NORMAL PLANAR, (NNA)2 CYCLIC RING, WITH A CISOID, RATHER THAN THE NORMAL TRANSOID, ARRANGEMENT OF AMIDO-SUBSTITUENTS (TMEDA=TETRAMETHYLETHYLENEDIAMINE)

被引：17

作者：

ANDREWS, PC ^{[1
]}

ARMSTRONG, DR ^{[1
]}

CLEGG, W ^{[1
]}

MACGREGOR, M ^{[1
]}

MULVEY, RE ^{[1
]}

机构：

[1] UNIV NEWCASTLE UPON TYNE,DEPT CHEM,NEWCASTLE TYNE NE1 7RU,TYNE & WEAR,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 07期

关键词：

D O I：

10.1039/c39910000497

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The red crystalline complex [PhCH2(Me)NNa(tmeda)]2, synthesised from equimolar proportions of PhNa, the secondary amine PhCH2(Me)NH and the Lewis base tmeda (tetramethylethylenediamine, Me2NCH2CH2NMe2), has been structurally identified by X-ray diffraction studies, which reveals a new type of structure based on a buckled (NNa)2 dimeric ring with a cisoid arrangement of amido-substituents.

引用

页码：497 / 498

页数：2

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