HOMOLOGATION OF CARBOXYLIC-ACIDS BY IMPROVED METHODS BASED ON RADICAL CHAIN CHEMISTRY OF ACYL DERIVATIVES OF N-HYDROXY-2-THIOPYRIDONE

被引：30

作者：

BARTON, DHR

CHERN, CY

JASZBERENYI, JC

机构：

[1] Department of Chemistry, Texas A and M University, College Station

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 35期

关键词：

D O I：

10.1016/S0040-4039(00)61176-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Reaction of substituted terminal olefins with carbon radicals generated from carboxylic acids gives adducts that can be transformed to one carbon atom longer homo-acids in high overall yield. With 6b yields are very good and the conditions of hydrolysis exceptionally mild.

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页码：5013 / 5016

页数：4

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