HOMOLOGATION OF CARBOXYLIC-ACIDS BY IMPROVED METHODS BASED ON RADICAL CHAIN CHEMISTRY OF ACYL DERIVATIVES OF N-HYDROXY-2-THIOPYRIDONE

被引:30
作者
BARTON, DHR
CHERN, CY
JASZBERENYI, JC
机构
[1] Department of Chemistry, Texas A and M University, College Station
关键词
D O I
10.1016/S0040-4039(00)61176-0
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Reaction of substituted terminal olefins with carbon radicals generated from carboxylic acids gives adducts that can be transformed to one carbon atom longer homo-acids in high overall yield. With 6b yields are very good and the conditions of hydrolysis exceptionally mild.
引用
收藏
页码:5013 / 5016
页数:4
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