CATALYSIS OF PHOSPHINE-COORDINATED RHODIUM(I) COMPLEXES FOR 2-PROPANOL DEHYDROGENATION

被引：20

作者：

MATSUBARA, T

SAITO, Y

机构：

[1] UNIV TOKYO,FAC ENGN,DEPT IND CHEM,BUNKYO KU,TOKYO 113,JAPAN

[2] HIMEJI INST TECHNOL,FAC ENGN,DEPT APPL CHEM,HIMEJI,HYOGO 67122,JAPAN

来源：

JOURNAL OF MOLECULAR CATALYSIS | 1994年 / 92卷 / 01期

关键词：

DEHYDROGENATION; PHOSPHINE COMPLEXES; PROPANOL; RHODIUM;

D O I：

10.1016/0304-5102(94)00033-6

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The Wilkinson complex RhCl(PPh3)3, which is inactive for 2-propanol dehydrogenation, exhibited its catalytic activity by adding Et3N, or by using a hydride complex, instead of chloride, for ketone hydrogenation as well. The elemental steps of the proposed dehydrogenation cycle was investigated with EHMO method.

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页码：1 / 8

页数：8

相关论文

共 25 条

[1] HYDRIDE TRANSFER REACTIONS CATALYSED BY RHODIUM-TIN COMPLEXES [J].

CHARMAN, HB .

JOURNAL OF THE CHEMICAL SOCIETY B-PHYSICAL ORGANIC, 1970, (04) :584-&

[2] HYDROGENATION OF OLEFINS CATALYZED BY THE CHLOROTRIS(TRIPHENYLPHOSPHINE)RHODIUM(I) COMPLEX - THEORETICAL-STUDY OF THE STRUCTURAL ASPECTS [J].

DEDIEU, A .

INORGANIC CHEMISTRY, 1980, 19 (02) :375-383

[3] THE PHOTOCHEMICAL DECOMPOSITION OF ALCOHOLS CATALYZED BY TRI(ISOPROPYL) PHOSPHINE COMPLEXES OF RHODIUM(I) [J].

DELGADOLIETA, E ;

LUKE, MA ;

JONES, RF ;

COLEHAMILTON, DJ .

POLYHEDRON, 1982, 1 (11-1) :839-840

[4]

DEWHIRST KC, 1974, INORG SYNTH, V15, P58

[5]

DEWHIRST KC, 1968, INORG CHEM, V7, P513

[6] COMPLEXES OF PLATINUM METALS .7. HOMOGENEOUS RUTHENIUM AND OSMIUM CATALYSTS FOR DEHYDROGENATION OF PRIMARY AND SECONDARY ALCOHOLS [J].

DOBSON, A ;

ROBINSON, SD .

INORGANIC CHEMISTRY, 1977, 16 (01) :137-142

[7]

FRAGALE C, 1977, J MOL CATAL, V5, P65

[8] PHOSPHINERHODIUM COMPLEXES AS HOMOGENEOUS CATALYSTS .10. HOMOGENEOUS HYDROGENATION OF KETONES USING PHOSPHINERHODIUM CATALYSTS MODIFIED WITH TRIETHYLAMINE [J].

HEIL, B ;

TOROS, S ;

BAKOS, J ;

MARKO, L .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1979, 175 (02) :229-232

[9] FURTHER STUDIES ON HOMOGENEOUS HYDROGENATION OF OLEFINS USING TRIS(TRIPHENYLPHOSPHINE)HALOGENORHODIUM(I) CATALYSTS [J].

JARDINE, FH ;

OSBORN, JA ;

WILKINSO.G .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1967, (10) :1574-&

[10] DEHYDROGENATION OF ALCOHOLS AND HYDROGENATION OF ALDEHYDES USING HOMOGENEOUS RUTHENIUM CATALYSTS [J].

JUNG, CW ;

GARROU, PE .

ORGANOMETALLICS, 1982, 1 (04) :658-666