REACTIONS IN MOLECULAR CLUSTERS FOLLOWING PHOTOIONIZATION

被引：86

作者：

BRUTSCHY, B

机构：

[1] Freie Universität Berlin, Institut für Physikalische und Theoretische Chemie, D1000 Berlin 33

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1990年 / 94卷 / 24期

关键词：

D O I：

10.1021/j100387a006

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

This article presents a review of our recent work on photoionization mass spectrometry of molecular aggregates, with both one- and two-photon ionization. The energetics and dynamics of solvated ions have been studied. Charge transfer and chemical reactions have been observed, exhibiting pronounced size effects. The reactive behavior of mixed clusters has in some cases been found to deviate strongly from that observed in gas-phase ion-molecule reactions. © 1990 American Chemical Society.

引用

页码：8637 / 8647

页数：11

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