PALLADIUM-CATALYZED ADDITION OF TIN-TIN AND TIN-SILICON BONDS TO ALLENES

被引：66

作者：

MITCHELL, TN

SCHNEIDER, U

机构：

[1] Fachbereich Chemie, Universität Dortmund, W-4600 Dortmund 50

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 407卷 / 03期

关键词：

D O I：

10.1016/0022-328X(91)86310-M

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Hexamethyl-, hexaethyl- and hexabutyl-ditin add to a variety of allenes in the presence of Pd(PPh3)4; the reaction is reversible. Trimethylsilyltrimethyl- and -tributyl-stannane also add under comparable conditions, the silyl moiety becoming attached to the central carbon atom of the allene skeleton; this reaction is, however, apparently not reversible.

引用

页码：319 / 327

页数：9

共 16 条

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