FUNCTIONALIZED CHLOROENAMINES IN AMINOCYCLOPROPANE SYNTHESIS .11. BICYCLO[3.1.0]HEXANE DERIVATIVES PREFERRING A CHAIR CONFORMATION

被引：11

作者：

VILSMAIER, E

FATH, J

TETZLAFF, C

MAAS, G

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | 1993年 / 10期

关键词：

D O I：

10.1039/p29930001895

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

endo-endo-3,6-Diaminobicyclo[3.1.0]hexane species 6 prefer a chair conformation. This has been established by X-ray structure analysis of derivative 6c and by H-1 and C-13 NMR spectroscopic analysis of compounds 6a and 6b. Intramolecular hydrogen bonding in 13, the monoammonium salt of 6b, can change the conformational situation.

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页码：1895 / 1900

页数：6

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