PSEUDOHALOGENO METAL-COMPOUNDS .75. PENTACARBONYLRHENIUM AND TRIPHENYLPHOSPHINEGOLD COMPLEXES OF PSEUDOHALIDE ANIONS - (OC)5REX, PH3PAUX (X=ONC(CN)2, O-MEC6H4SO2C(CN)2, O-MEC6H4SO2NCN, PH2(S)PNCN)

被引：33

作者：

FRITSCH, E

POLBORN, K

SUNKEL, K

BECK, W

KOHLER, H

JAGER, L

机构：

[1] UNIV MUNICH,INST ANORGAN CHEM,MEISERSTR 1,W-8000 MUNICH 2,GERMANY

[2] MARTIN LUTHER UNIV,SEKT CHEM,O-4010 HALLE,GERMANY

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1992年 / 617卷 / 11期

关键词：

PENTACARBONYLRHENIUM COMPLEXES; NITROSODICYANMETHANIDE; O-TOSYLDICYANMETHANIDE; O-TOSYLCYANAMIDE; DIPHENYLTHIOPHOSPHORYLCYANAMIDE;

D O I：

10.1002/zaac.19926170119

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The pseudohalides (X-) nitrosodicyanmethanide, o-tosyldicyammethanide, o-tosylcyanamide and diphenylthiophosphinylcyanamide react with the Organometallic Lewis Acids (OC)5Re' (as (OC)5ReFBF3) and Ph3PAu+ (as Ph3PAuNO3) to give the neutral title complexes (OC)5Re-X and Ph3PAu-X, respectively. X-ray diffraction shows that nitroso-dicyanmethanide is coordinated through the nitroso N-atom to the Re(CO), fragment. Cyanide-N-coordination is observed for the complexes with o-tosyldicyanmethanide and o-tosylcyanamide whereas diphenylthiophosphinylcyanamide is S-coordinated to the gold atom. Spectroscopic data (IR, NMR) of 1-6 are described.

引用

页码：110 / 116

页数：7

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