REACTION OF (BUTADIENE)ZIRCONOCENE WITH TRIS(PENTAFLUOROPHENYL)BORANE - A NOVEL WAY OF GENERATING METHYLALUMOXANE-FREE HOMOGENEOUS ZIEGLER-TYPE CATALYSTS

被引：179

作者：

TEMME, B ^{[1
]}

ERKER, G ^{[1
]}

KARL, J ^{[1
]}

LUFTMANN, H ^{[1
]}

FROHLICH, R ^{[1
]}

KOTILA, S ^{[1
]}

机构：

[1] UNIV MUNSTER, INST ORGAN CHEM, D-48149 MUNSTER, GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 1995年 / 34卷 / 16期

关键词：

ALKENES; POLYMERIZATION; SANDWICH COMPLEXES; ZIEGLER CATALYSTS; ZIRCONIUM COMPOUNDS;

D O I：

10.1002/anie.199517551

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An active catalyst for α‐olefin polymerization without addition of activator components has been discovered in the betain 2, which is formed in the title reaction shown below. Laser desorption mass spectrometry shows that B(C6F5)3‐containing polymers with a molecular weight distribution typical of Ziegler catalysts are formed. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：1755 / 1757

页数：3

共 43 条

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[42] 1,3-DIENE COMPLEXES OF ZIRCONIUM AND HAFNIUM PREPARED BY THE REACTION OF ENEDIYLMAGNESIUM WITH MCL2CP2 - A REMARKABLE DIFFERENCE BETWEEN THE ZIRCONIUM AND HAFNIUM ANALOGS AS REVEALED BY H-1-NMR AND ELECTRONIC-SPECTRA [J].

YASUDA, H ;

KAJIHARA, Y ;

MASHIMA, K ;

NAGASUNA, K ;

LEE, K ;

NAKAMURA, A .

ORGANOMETALLICS, 1982, 1 (02) :388-396

[43]

[No title captured]

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