HEPTALENEBIS(TRICARBONYLIRON)

被引：22

作者：

VOGEL, E

KERIMIS, D

ALLISON, NT

ZELLERHOFF, R

WASSEN, J

机构：

[1] Institut für Organische Chemie, Universität Köln, Köln, D-5000

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1979年 / 18卷 / 07期

关键词：

D O I：

10.1002/anie.197905451

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis of substituted heptalenes, e.g 3 and 4, can be accomplished via the bis(tricarbonyliron) derivative 2 formed from 1 and benzylideneacetone(tricarbonyliron). This entry into the chemistry of substituted heptalenes is facilitated by a new heptalene synthesis involving protection of the central double bond of isotetralin by epoxidation. (Figure Presented.) Copyright © 1979 by Verlag Chemie, GmbH, Germany

引用

页码：545 / 546

页数：2

共 20 条

[1]

BIRCH AJ, 1976, TRANSITION METAL ORG, V1, P1

[2] NEW METHODS FOR OXIDATION OF ALDEHYDES TO CARBOXYLIC ACIDS AND ESTERS [J].