ASYMMETRIC GRIGNARD ADDITION TO ALDEHYDES - AN EXAMPLE OF INVERSE TEMPERATURE-DEPENDENCE OF ENANTIOMERIC EXCESS

被引：19

作者：

MARKO, IE ^{[1
]}

CHESNEY, LA ^{[1
]}

HOLLINSHEAD, DM ^{[1
]}

机构：

[1] ZENECA PHARMACEUT, MACCLESFIELD SK10 4TG, CHESHIRE, ENGLAND

来源：

TETRAHEDRON-ASYMMETRY | 1994年 / 5卷 / 04期

关键词：

D O I：

10.1016/0957-4166(94)80020-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The addition of organomagnesium derivatives to aldehydes, promoted by chiral diamine 3 shows an inverse correlation between ee and temperature.

引用

页码：569 / 572

页数：4

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