A LANTHANUM(III) COMPLEX OF A 6-NITROGEN DONOR MACROCYCLIC LIGAND WITH AROMATIC SIDE-CHAINS - SYNTHESIS, CRYSTAL-STRUCTURE AND SPECTRA

被引：5

作者：

BENETOLLO, F

BOMBIERI, G

VALLARINO, LM

机构：

[1] UNIV MILAN,IST CHIM FARMACEUT,VIALE ABRUZZI 42,I-20131 MILAN,ITALY

[2] CNR,IST CHIM & TECNOL INORGAN & MAT,I-35100 PADUA,ITALY

[3] VIRGINIA COMMONWEALTH UNIV,DEPT CHEM,RICHMOND,VA 23284

来源：

POLYHEDRON | 1994年 / 13卷 / 04期

关键词：

D O I：

10.1016/S0277-5387(00)84734-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Yellow crystals of formula [La(CH3COO)(NCS)2(C26H18N6)] were synthesized by the condensation of 1,2-diaminobenzene and 2,6-pyridinedicarboxyaldehyde in the presence of lanthanum(III) acetate, followed by partial acetate-thiocyanate metathesis. The complex has been characterized by X-ray crystallography. The La(III) ion is 10-coordinate, being linked to the six nitrogen atoms of the macrocyclic ligand, to the nitrogen atoms of two isothiocyanates situated on opposite sides of the macrocycle and to a bidentate chelating acetate. The IR and NMR spectra (H-1 and C-13) of the complex were recorded and assigned.

引用

页码：573 / 578

页数：6