GRIGNARD-TYPE ADDITION OF ALKENYLZIRCONOCENE AND ALKYLZIRCONOCENE CHLORIDE TO ALDEHYDE - REMARKABLE CATALYTIC ACCELERATION EFFECT OF AGCLO4

被引：49

作者：

MAETA, H ^{[1
]}

HASHIMOTO, T ^{[1
]}

HASEGAWA, T ^{[1
]}

SUZUKI, K ^{[1
]}

机构：

[1] KEIO UNIV,DEPT CHEM,KOHOKU KU,YOKOHAMA,KANAGAWA 223,JAPAN

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 40期

关键词：

D O I：

10.1016/S0040-4039(00)61101-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Nucleophilic addition of alkenylzirconocene chloride [Cp2Zr(Cl)CH=CHR] to aldehyde, which is ordinarily a slow reaction, is remarkably accelerated by a catalytic amount of AgClO4. The rate acceleration effect is also valid for the alkyl congener, Cp2Zr(Cl)R.

引用

页码：5965 / 5968

页数：4

共 14 条

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