MASS SPECTROMETRY IN STRUCTURAL AND STEREOCHEMICAL PROBLEMS .170. A STUDY OF EFFECT OF RING SIZE IN RECIPROCAL HYDROGEN TRANSFER

被引：14

作者：

EADON, G

DJERASSI, C

机构：

[1] Department of Chemistry, Stanford University, Stanford, California

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1969年 / 91卷 / 10期

关键词：

D O I：

10.1021/ja01038a052

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Recent reports of nonspecific hydrogen migrations involving large ring transition states prompted an investigation into the relationship between ring size and the facility of hydrogen transfer. Using 2-(1ʹ-octyl)-cyclohexanone as a model compound for reciprocal hydrogen transfer, deuterium labeling confirms that ring size plays a crucial role in determining the ease of hydrogen migration. © 1969, American Chemical Society. All rights reserved.

引用

页码：2724 / &

共 23 条

[1] ADAMS R, 1932, ORG SYNTH, V1, P250
[2] DEUTERIUM LABELING OF 2-UNDECANONE VIA GAS-LIQUID CHROMATOGRAPHY
ALBERT, DK
MEYERSON, S
[J]. ANALYTICAL CHEMISTRY, 1967, 39 (14) : 1904 - &
[3] MASS SPECTROMETRY IN STRUCTURAL + STEREOCHEMICAL PROBLEMS .35. MASS SPECTROMETRIC FRAGMENTATION + HYDROGEN TRANSFER REACTIONS IN 16-KETO STEROIDS . NOVEL SYNTHESIS OF SIDE CHAIN LABELED CHOLESTANES
BEARD, C
DJERASSI, C
BUDZIKIEWICZ, H
WILSON, JM
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1964, 86 (02) : 269 - &
[4] MASS SPECTROMETRY AND ITS APPLICATION TO STRUCTURAL AND STEREOCHEMICAL PROBLEMS .167. LONG CHAIN HYDROGEN TRANSFER IN MASS SPECTROMETRY
BRANDT, R
DJERASSI, C
[J]. HELVETICA CHIMICA ACTA, 1968, 51 (07) : 1750 - &
[5] MASS SPECTROMETRY IN STRUCTURAL AND STEREOCHEMICAL PROBLEMS .92. FURTHER STUDIES ON MCLAFFERTY REARRANGEMENT OF ALIPHATIC KETONES
BUDZIKIEWICZ, H
FENSELAU, C
DJERASSI, C
[J]. TETRAHEDRON, 1966, 22 (04) : 1391 - +
[6] BUDZIKIEWICZ H, 1967, MASS SPECTROMETRIC I
[7] MASS SPECTROMETRY IN STRUCTURAL AND STEREOCHEMICAL PROBLEMS .144. UNUSUAL FRAGMENTATIONS IN LOW-VOLTAGE SPECTRA OF ALIPHATIC KETONES
CARPENTER, W
DUFFIELD, AM
DJERASSI, C
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1968, 90 (01) : 160 - +
[8] DIEKMAN J, 1969, J AM CHEM SOC, V91, P2069
[9] EHRENSTEIN M, 1960, J ORG CHEM, V15, P264
[10] FIESER LF, 1965, REAGENTS ORGANIC SYN, P1180

← 1 2 3 →