MASS SPECTROMETRY IN STRUCTURAL AND STEREOCHEMICAL PROBLEMS .170. A STUDY OF EFFECT OF RING SIZE IN RECIPROCAL HYDROGEN TRANSFER

被引：14

作者：

EADON, G

DJERASSI, C

机构：

[1] Department of Chemistry, Stanford University, Stanford, California

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1969年 / 91卷 / 10期

关键词：

D O I：

10.1021/ja01038a052

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Recent reports of nonspecific hydrogen migrations involving large ring transition states prompted an investigation into the relationship between ring size and the facility of hydrogen transfer. Using 2-(1ʹ-octyl)-cyclohexanone as a model compound for reciprocal hydrogen transfer, deuterium labeling confirms that ring size plays a crucial role in determining the ease of hydrogen migration. © 1969, American Chemical Society. All rights reserved.

引用

页码：2724 / &

共 23 条

[11] EINFLUSS BEHINDERTER ROTATION SOWIE ANDERER ENERGETISCHER FAKTOREN AUF DIE MCLAFFERTY-UMLAGERUNG VON KETONEN
FRITZ, H
BUDZIKIE.H
DJERASSI, C
[J]. CHEMISCHE BERICHTE-RECUEIL, 1966, 99 (01): : 35 - &
[12] STEREOCHEMICAL INVESTIGATIONS OF CYCLIC BASES .2. HOFMANN DEGRADATION OF SOME CYCLIC QUATERNARY AMMONIUM SALTS
JEWERS, K
MCKENNA, J
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1958, (JUN): : 2209 - 2217
[13] MEYERSON S, 1963, ADV MASS SPECTROM, V2, P313
[14] PAUL R, 1935, B SOC CHIM FRANCE, P317
[15] RICHTER WJ, 1965, TETRAHEDRON LETT, P1235
[16] SONN M, 1965, J AM CHEM SOC, V87, P680
[17] A NEW METHOD FOR ALKYLATION OF KETONES AND ALDEHYDES - C-ALKYLATION OF MAGNESIUM SALTS OF N-SUBSTITUTED IMINES
STORK, G
DOWD, SR
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1963, 85 (14) : 2178 - &
[18] MASS SPECTRA OF DERIVATIVES OF O-AMINOBENZOIC ACID
TEETER, RM
[J]. ANALYTICAL CHEMISTRY, 1966, 38 (12) : 1736 - &
[19] VLIET EB, 1943, ORG SYNTH, V2, P416
[20] VOGEL AI, 1962, PRACTICAL ORGANIC CH, P288

← 1 2 3 →