Fe-C-Cr-V-Ti系高硼堆焊合金显微组织及耐磨性研究

被引:0
作者
李煌
机构
[1] 湘潭大学
关键词
药芯焊丝; 堆焊; 显微组织; 耐磨性; 硼化物;
D O I
暂无
年度学位
2010
学位类型
硕士
导师
摘要
鉴于高硼合金具有优良的耐磨粒磨损性能,且价格低,经济适用性好,原料来源有保证的特点,采用药芯焊丝埋弧堆焊的方法分别制备了加Ti和不加Ti含7.0%~17.0% Cr,0.7%~1.8% C,0~1.8% B(质量百分数,以下同)的Fe-C-Cr-V高硼堆焊合金,借助光学显微镜(OM)、X-射线衍射(XRD)、扫描电子显微镜(SEM)和电子能谱仪(EDS)等分析手段,对其显微组织、相组成及硬质相分布形貌等进行了分析。 首先,考察了药芯焊丝中B4C加入量对Fe-Cr-Ti-B堆焊合金硬度及耐磨性的影响,试验结果表明,含TiB2相的Fe-Cr-Ti-B堆焊合金的基体组织由大量铁素体和少量马氏体组成,而硬质相则由(Fe, Cr)3(C,B)+TiB2+TiC+(Fe,Cr)2B+(Fe,Cr)B等构成,因其含有TiB2、TiC等显微硬度高的硬质相而具有优良的耐磨性。随药芯焊丝中B4C含量的增加,其硬度及相对耐磨性ε先升高后降低,当其含量为5%时,达到最佳。 另外,研究了Cr、V、Ti、C、B等合金元素对Fe-C-Cr-V高硼堆焊合金显微组织、硬度以及耐磨性的影响,考察了外加载荷对Fe-C-Cr-V高硼堆焊合金磨损失重的影响。试验结果表明,Fe-C-Cr-V高硼堆焊合金基体组织由α-Fe组成,硬质相则包括M3(C, B)、M2B、VC、M8B等,其显微组织、硬度和耐磨性随着合金元素含量而改变,当堆焊合金成分为11% Cr,2% V,1.55% C,1.12% B时,性能最佳。此外,向该堆焊合金中加入一定量的钛,可使其显微组织细化,耐磨性显著提高。耐磨粒磨损试验结果显示,随着外加载荷增大,Fe-C-Cr-V高硼堆焊合金的磨损失重并不随之增大,而呈“Λ”形变化曲线,这与E. Rabnowicz提出的合金磨损量与外加载荷的磨粒微切削模型不符。
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页数:66
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[21]
The effect of boron on the wear behavior of iron-based hardfacing alloys for nuclear power plants valves.[J].Jeong Wan Yoo;Seong Hun Lee;Chong S. Yoon;Seon Jin Kim.Journal of Nuclear Materials.2006, 1
[22]
Microstructure change caused by (Cr;Fe) 23 C 6 carbides in high chromium Fe–Cr–C hardfacing alloys.[J].Chieh Fan;Ming-Che Chen;Chia-Ming Chang;Weite Wu.Surface & Coatings Technology.2006, 3
[23]
FeB/Fe2B phase transformation during SPS pack-boriding:: Boride layer growth kinetics [J].
Yu, LG ;
Chen, XJ ;
Khor, KA ;
Sundararajan, G .
ACTA MATERIALIA, 2005, 53 (08) :2361-2368
[24]
The effect of microstructure on abrasive wear of hardfacing alloys.[J].M.F. Buchely;J.C. Gutierrez;L.M. León;A. Toro.Wear.2005, 1
[25]
Abrasive wear behaviour of laser clad and flame sprayed-melted NiCrBSi coatings.[J]..Surface & Coatings Technology.2005, 24
[26]
Wear resistance of facing alloy with metastable austenite [J].
Filippov, MA ;
Kulishenko, BA ;
Val'kov, EV .
METAL SCIENCE AND HEAT TREATMENT, 2005, 47 (1-2) :6-8
[27]
Microstructural and microhardness characteristics of gas tungsten are synthesized Fe–Cr–C coating on AISI 4340.[J].Soner Buytoz;M. Mustafa Yildirim;Hulya Eren.Materials Letters.2004, 6
[28]
Development of hardfacing material in Fe-Cr-Nb-C system for use under highly abrasive conditions [J].
Scandella, F ;
Scandella, R .
MATERIALS SCIENCE AND TECHNOLOGY, 2004, 20 (01) :93-105
[29]
Wear behaviour of hardfacing deposits on cast iron.[J].S. Chatterjee;T.K. Pal.Wear.2003, 1
[30]
Abrasive wear of high speed steels: Influence of abrasive particles and primary carbides on wear resistance [J].
Badisch, E ;
Mitterer, C .
TRIBOLOGY INTERNATIONAL, 2003, 36 (10) :765-770