A CHIRAL BICYCLIC 1-ACETOXY PHOSPHONAMIDE

被引：5

作者：

BLAZIS, VJ

KOELLER, KJ

RATH, NP

SPILLING, CD

机构：

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1995年 / 51卷

关键词：

D O I：

10.1107/S0108270194007948

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The crystal structure of a chiral non-racemic 1-acetoxy phosphonamide, 2-(1-acetoxy-3-methylbutyl)-1,3-(2,2-dimethylpropyl)-2,3,3a,4,5,6,7,7a-octahydro-1H-1,3,2-benzodiazaphosphole 2-oxide, m.p. = 385.5-386 K, C23H45N2O3P, has been determined by X-ray diffraction. The title compound consists of a five-membered ring with a tetrahedrally coordinated P atom. In addition to the two N atoms of the five-membered ring, the P atom is bonded to an O atom and the C-1 atom of the acetoxylalkyl chain. The five-membered ring is trans fused to a cyclohexane ring in a chair conformation.

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页码：86 / 88

页数：3

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