ELECTRIC-FIELD EFFECTS ON ZERO-KINETIC-ENERGY PHOTOELECTRON-SPECTRA - AN EXPLANATION OF OBSERVED TRENDS

被引：78

作者：

MERKT, F

FIELDING, HH

SOFTLEY, TP

机构：

[1] Physical Chemistry Laboratory, Oxford, OX1 3QZ, South Parks Road

来源：

CHEMICAL PHYSICS LETTERS | 1993年 / 202卷 / 1-2期

关键词：

D O I：

10.1016/0009-2614(93)85365-U

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

An explanation is offered for the propensity for large negative changes of rotational angular momentum in ZEKE photoelectron spectra, which is increasingly observed as the rotational constant of the photoion decreases; Stark mixing becomes progressively more important, facilitating multistep rotational autoionization processes. The Inglis-Teller limit serves as a useful benchmark for assessing the importance of electric field effects. A discussion is presented of the relative importance of l mixing and J mixing.

引用

页码：153 / 160

页数：8

共 26 条

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