REGIOSELECTIVE PALLADIUM(0) CATALYZED AZIDATION AND AMINATION OF 1-ALKENYLCYCLOPROPYL ESTERS - A NEW ROUTE TO 2,3-METHANOAMINO ACIDS

被引：36

作者：

AUFRANC, P

OLLIVIER, J

STOLLE, A

BREMER, C

ESSAYED, M

DEMEIJERE, A

SALAUN, J

机构：

[1] UNIV GOTTINGEN,INST ORGAN CHEM,W-3400 GOTTINGEN,GERMANY

[2] UNIV PARIS 11,INST CHIM MOLEC ORSAY,CNRS,CARBOCYLES LAB,F-91405 ORSAY,FRANCE

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 26期

关键词：

D O I：

10.1016/S0040-4039(00)60525-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Palladium (0) catalyzed azidation of 1-alkenylcyclopropyl esters provides regioselectively 1-azido-1-alkenyl cyclopropanes, convenient precursors of 2,3-methanoamino acids. On the other hand, amination occurred exclusively on the less substituted allylic end, providing strained 2-cyclopropylideneethylamine derivatives.

引用

页码：4193 / 4196

页数：4

共 21 条

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