Thermal anomalies in aqueous systems: Manifestations of interfacial phenomena?

被引：33

作者：

Drost-Hansen, W. ^{[1
]}

机构：

[1] Univ Miami, Inst Marine Sci, Miami, FL 33152 USA

来源：

CHEMICAL PHYSICS LETTERS | 1968年 / 2卷 / 08期

关键词：

D O I：

10.1016/0009-2614(63)80042-1

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

It is proposed that the structure of water near certain interfaces is different from that of bulk water and that this vicinal water readily undergoes structural transitions at discrete temperatures. This phenomenon may, in part, be responsible for the often reported thermal anomalies ("kinks") in aqueous systems.

引用

页码：647 / 652

页数：6

共 52 条

[1] FINE-STRUCTURE DISCONTINUITIES IN INTERMOLECULAR ACTIVATION ENERGY OF FLOW OF 2 TO 30 PER CENT AQUEOUS ETHYL ALCOHOL [J].