AN IMPROVED ROUTE TO 1,2,4-TRIOXANES USING TIN(IV) AS A HYDROGEN EQUIVALENT

被引：8

作者：

CAI, JQ ^{[1
]}

DAVIES, AG ^{[1
]}

机构：

[1] UNIV LONDON UNIV COLL,DEPT CHEM,20 GORDON ST,LONDON WC1H 0AJ,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1992年 / 24期

关键词：

D O I：

10.1039/p19920003383

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Bloodworth's route to the 1,2,4-trioxanes has been duplicated using tin(IV) as a hydrogen equivalent throughout. Thus a tetraallyltin compound is treated with singlet oxygen to give a tetraallylperoxytin compound; this adds to an aldehyde to give the tin derivative of a peroxyhemiacetal, and this tin alkoxide undergoes ring-closing intramolecular addition to the olefinic group in the presence of mercury(II) acetate to give the 1,2,4-trioxane.

引用

页码：3383 / 3386

页数：4

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