COMPLEMENTARY REGIOSELECTION IN NUCLEOPHILE ADDITIONS TO CATIONIC ETA-5-CYCLOHEXADIENYL IRON COMPLEXES

被引：19

作者：

STEPHENSON, GR

HOWARD, PW

OWEN, DA

WHITEHEAD, AJ

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 09期

关键词：

D O I：

10.1039/c39910000641

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

1-Alkoxy and 1-acetoxy substituted tricarbonyl(eta-5-cyclohexadienyl)iron(1+) complexes undergo reactions with nucleophiles at opposite ends of the pi-system in a reversal of regiocontrol that offers novel possibilities for complementary control strategies in applications in asymmetric synthesis, since the two series of complexes can be obtained from the same precursor.

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页码：641 / 642

页数：2

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