ASYMMETRIC-SYNTHESIS OF ALLYLSILANES BY PALLADIUM-CATALYZED ASYMMETRIC REDUCTION OF ALLYLIC CARBONATES WITH FORMIC-ACID

被引：53

作者：

HAYASHI, T ^{[1
]}

IWAMURA, H ^{[1
]}

UOZUMI, Y ^{[1
]}

机构：

[1] HOKKAIDO UNIV,GRAD SCH PHARMACEUT SCI,SAPPORO 060,JAPAN

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 27期

关键词：

D O I：

10.1016/S0040-4039(00)76975-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Reduction of 3-alkyl-3-trialkylsilyl-2-propenyl methyl carbonates with formic acid and 1,8-bis(dimethylamino)naphthalene in the presence of a palladium catalyst (3 mol %) coordinated with (R)-3-diphenylphosphino-3'-methoxy-4 4'-biphenanthryl (MOP-phen) gave optically active allylsilanes (3-alkyl-3-trialkylsilyl-1 -propenes) of up to 91% ee.

引用

页码：4813 / 4816

页数：4

共 33 条

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