REACTIONS OF THE TUNGSTEN CARBONYL ETA(2)-TRITYLALLENE COMPLEX - CRYSTAL-STRUCTURE OF 2 ALLENE COMPLEXES

被引：14

作者：

LEE, L ^{[1
]}

WU, IY ^{[1
]}

LIN, YC ^{[1
]}

LEE, GH ^{[1
]}

WANG, Y ^{[1
]}

机构：

[1] NATL TAIWAN UNIV,DEPT CHEM,TAIPEI 10764,TAIWAN

来源：

ORGANOMETALLICS | 1994年 / 13卷 / 06期

关键词：

D O I：

10.1021/om00018a057

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reactions of cationic tungsten eta2-tritylallene complex [CP(CO)3W(eta2-CH2=C=CHCPh3)]BF4, 1 (Cp = eta5-C5H5, Ph = C6H5), with PhCH2NHLi and NaN3 give CP(CO)2W[eta3-CH2C(CONHCH2Ph)CHCPh3],2, and cis-CP(CO)2W(NCO)(eta2=CH2=C=CHCPh3), 3, respectively. In the reaction of 3 with CF3COOH the NCO ligand is replaced, giving CiS-Cp(CO)2W(OCOCF3)(eta2-CH2=C= CHCPh3), 4. The structures of 3 and 4 have been determined by X-ray diffraction studies.

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页码：2521 / 2526

页数：6

相关论文

共 47 条

[31] THE SYNTHESIS OF ALKOXYCARBONYL, CARBAMOYL AND ISOCYANATO COMPLEXES, FAC-M(CO)3(P-P)Z [M=MN, RE - P-P=DPPE, DPPP - Z=C(O)OME, C(O)OET, C(O)NHPRN, NCO] - THE SINGLE-CRYSTAL STRUCTURES OF FAC-MN(CO)3(DPPP)C(O)OET AND FAC-MN(CO)3(DPPE)NCO [J].

MANDAL, SK ;

HO, DM ;

ORCHIN, M .

POLYHEDRON, 1992, 11 (16) :2055-2063

[32]

MANNING AR, 1978, J ORGANOMET CHEM, V157, P239

[33] METAL-CARBONYL AND METAL-NITROXYL COMPLEXES .10. PHOTOCHEMICAL GENERATION OF ORGANOMETALLIC NITRENES AND CRYSTAL STRUCTURE OF A CARBONYLATION PRODUCT, ISOCYANATOCARBONYL-PI-CYCLOPENTADIENYLBIS(TRIPHENYLPHOSPHINE)MOLYBDENUM [J].

MCPHAIL, AT ;

GROSS, PM ;

KNOX, GR ;

ROBERTSO.CG ;

SIM, GA .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1971, (02) :205-&

[34] MOLECULAR-STRUCTURE OF BIS(TRIPHENYLPHOSPHINE)ALLENEPALLADIUM [J].

OKAMOTO, K ;

KAI, Y ;

YASUOKA, N ;

KASAI, N .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1974, 65 (03) :427-441

[35]

Otsuka S., 1976, ADV ORGANOMET CHEM, V14, P245

[36] SYNTHESIS AND REACTIVITY OF [1,4,7-TRIAZACYCLONONANE RE(NO)(CO)(NCO)]+- KINETICS AND MECHANISMS OF ITS FORMATION AND TRANSFORMATION TO [LRE(NO)(CO)NH3]N+ (LRE(NO)(CO)CL)N+, (LRE(NO)(CO)HCO2-)N+, (LRE(NO)(CO)CF3SO3-)N+ AND OTHER SPECIES - CRYSTAL-STRUCTURE OF [LRE(NO)(CO)(NH3)]BR2 [J].

POMP, C ;

WIEGHARDT, K ;

NUBER, B ;

WEISS, J .

INORGANIC CHEMISTRY, 1988, 27 (21) :3789-3796

[37] SYNTHESIS, STRUCTURE, AND REACTIVITY OF ALLENE COMPLEXES OF THE CHIRAL RHENIUM FRAGMENT [(ETA-5-C5H5)RE(NO)(PPH3)]+ [J].

PU, JQ ;

PENG, TS ;

ARIF, AM ;

GLADYSZ, JA .

ORGANOMETALLICS, 1992, 11 (10) :3232-3241

[38]

RACANELLI P, 1969, J CHEM SOC CHEM COMM, P361

[39] REACTION OF DICARBONYL(PENTAHAPTO-CYCLOPENTADIENYL)-(OLEFIN)IRON CATIONS WITH SODIUM AZIDE [J].

ROSAN, A ;

ROSENBLU.M .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1974, 80 (01) :103-107

[40]

ROUSTAN JC, 1979, J ORGANOMET CHEM, V168, P610

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