STEREOSELECTIVE INDUCTION OF AN AXIAL CHIRALITY BY SUZUKI CROSS-COUPLING OF TRICARBONYL(ARENE)CHROMIUM COMPLEXES WITH ARYLBORONIC ACIDS

被引：51

作者：

UEMURA, M

KAMIKAWA, K

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 23期

关键词：

D O I：

10.1039/c39940002697

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Tricarbonyl(2,6-disubstituted-1-bromobenzene)chromium was treated with ortho-substituted phenylboronic acids in the presence of a palladium(0) catalyst to give mono-Cr(CO)(3) complexes of biphenyl compounds with a complementary axial chirality depending upon the nature of ortho-substituent of the phenylboronic acids.

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页码：2697 / 2698

页数：2

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