TOTAL SYNTHESIS OF CYCLOPENTENOPORPHYRINS OF SEDIMENTARY ORIGIN - DEOXOPHYLLOERYTHROETIOPORPHYRIN, CHLOROPHYLL-C FOSSILS AND RELATED-COMPOUNDS

被引：37

作者：

BAUDER, C ^{[1
]}

OCAMPO, R ^{[1
]}

CALLOT, HJ ^{[1
]}

机构：

[1] UNIV STRASBOURG 1,INST CHIM,CNRS,URA 31,1 RUE BLAISE PASCAL,F-67070 STRASBOURG,FRANCE

来源：

TETRAHEDRON | 1992年 / 48卷 / 24期

关键词：

SEDIMENTARY PORPHYRINS; CHLOROPHYLL GEOCHEMISTRY; TOTAL SYNTHESIS; E-RING FORMATION;

D O I：

10.1016/S0040-4020(01)90123-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

This article describes the total synthesis of seven porphyrins, fossils of chlorophyll derivatives, isolated from sedimentary sources and possess five-membered rings fused to the porphyrin nucleus, this additional ring being placed between positions 13,15 or 15,17. This ring was built from vinyl, hydroxyethyl or isopropenyl groups under strong acidic conditions.

引用

页码：5135 / 5150

页数：16

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