PREPARATION, CHARACTERIZATION, AND REACTIONS OF THE 1ST PARENT ACETYLENE FISCHER CARBENE COMPLEXES

被引：56

作者：

RAHM, A

WULFF, WD

RHEINGOLD, AL

机构：

[1] UNIV CHICAGO,DEPT CHEM,SEARLE CHEM LAB,CHICAGO,IL 60637

[2] UNIV DELAWARE,DEPT CHEM,NEWARK,DE 19716

来源：

ORGANOMETALLICS | 1993年 / 12卷 / 03期

关键词：

D O I：

10.1021/om00027a002

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The parent acetylenic Fischer carbene complexes of the type 2, (CO)5M=C(NMe2)C=CH, are isolated and characterized as both chromium (2a) and tungsten(2b) derivatives. Their Diels-Alder and Michael addition reactions are described, as well as the deprotonation of their acetylenic hydrogens.

引用

页码：597 / 599

页数：3

共 32 条

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