SYNTHESIS OF A NOVEL OPTICALLY-ACTIVE C-2-SYMMETRICAL 2,2'-BIPYRIDINE

被引：33

作者：

BOLM, C ^{[1
]}

EWALD, M ^{[1
]}

ZEHNDER, M ^{[1
]}

NEUBURGER, MA ^{[1
]}

机构：

[1] UNIV BASEL,INST ANORGAN CHEM,CH-4056 BASEL,SWITZERLAND

来源：

CHEMISCHE BERICHTE-RECUEIL | 1992年 / 125卷 / 02期

关键词：

2,2'-BIPYRIDINE; CHIRAL LIGAND; PALLADIUM COMPLEXES; COPPER COMPLEXES; COBALT COMPLEXES;

D O I：

10.1002/cber.19921250224

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Optically active 2,2'-bipyridine (S,S)-1 was synthesized by radical cyclization and a nickel(0)-mediated coupling of enantiomerically pure bromopyridine (S)-8. Palladium, copper, and cobalt complexes of 1 were prepared. The solid-state structures of meso-1 and 11 were determined by X-ray crystal structure analysis.

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页码：453 / 458

页数：6

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