RING EXPANSIONS OF 2-HALOETHYNYL-2-NORBORNANOLS

被引：28

作者：

DJUARDI, E ^{[1
]}

BOVONSOMBAT, P ^{[1
]}

MCNELIS, E ^{[1
]}

机构：

[1] NYU,DEPT CHEM,NEW YORK,NY 10003

来源：

TETRAHEDRON | 1994年 / 50卷 / 41期

关键词：

D O I：

10.1016/S0040-4020(01)89294-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

2-Haloethynyl-2-norbomanols react with iodine and Koser's reagent in acetonitrile to afford two ring-expanded products, 2-[(Z)-haloiodomethylidene]bicyclo[3.2.1]octan-3-one and 3-[(Z)-haloiodomethylidene]bicyclo[3.2.1]octan-2-one. These results contrast with the 2-haloethynyl-2-bomanols which lead to the corresponding 3-octanones.

引用

页码：11793 / 11802

页数：10

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